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Immediately following a spill at sea, released oil—ranging from diesel to light crude and diluted bitumen, will initially weather through evaporation, resulting in an elevated concentration of light hydrocarbons in the air. As part of oil spill response operations, first responders use hand-held devices to monitor airborne concentrations when approaching a spill. The feasibility of using numerical modelling as an additional tool to assess potential flammability and plan response operations in the spill area was explored in this study. The Lower Explosive Limit(LEL) is defined as the minimum concentration of a gas in air, in this case a mixture of evaporated hydrocarbons, which can produce a flash fire in the presence of an ignition source. This ignition source could be triggered by the vessel itself or by spill response operations. A framework was put into place, utilizing a threedimensional hydrodynamic model(H3D), an oil spill model(SPILLCALC), and an air dispersion model(CALPUFF) to assess the risk of possible ignition of the hydrocarbon vapour in the event of a spill. The study looked at a hypothetical credible worst case tanker spill(16 500 m~3) of diluted bitumen(cold lake winter blend)occurring at Arachne Reef in Haro Strait, British Columbia, Canada. SPILLCALC provided one-minute averaged vapour fluxes from the water surface for each of 17 modelled pseudo-components which were used as inputs to CALPUFF. Using the predicted airborne concentrations of each pseudo-component, time-scaled to one-second averages, the flammability potential in the immediate spill area was determined at each grid point using Le Chatelier's mixing equation. The approach describe here was developed as a proof of concept, and could be established as a real-time system, bringing valuable information in addition to hand-held devices during a spill response, or during a response exercise. This modelling study was conducted as part of Kinder Morgan's Trans Mountain Pipeline Expansion Project. There are a number of commercially available oil spill models but few if any are equipped with the ability to model air dispersion and forecast hazardous conditions as discussed in this paper. 相似文献
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Intermineral oxygen three‐isotope systematics of silicate minerals in equilibrated ordinary chondrites 
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下载免费PDF全文 David McDougal Daisuke Nakashima Travis J. Tenner Noriko T. Kita John W. Valley Takaaki Noguchi 《Meteoritics & planetary science》2017,52(11):2322-2342
High‐precision oxygen three‐isotope ratios were measured for four mineral phases (olivine, low‐Ca and high‐Ca pyroxene, and plagioclase) in equilibrated ordinary chondrites (EOCs) using a secondary ion mass spectrometer. Eleven EOCs were studied that cover all groups (H, L, LL) and petrologic types (4, 5, 6), including S1–S4 shock stages, as well as unbrecciated and brecciated meteorites. SIMS analyses of multiple minerals were made in close proximity (mostly <100 μm) from several areas in each meteorite thin section, to evaluate isotope exchange among minerals. Oxygen isotope ratios in each mineral become more homogenized as petrologic type increases with the notable exception of brecciated samples. In type 4 chondrites, oxygen isotope ratios of olivine and low‐Ca pyroxene are heterogeneous in both δ18O and Δ17O, showing similar systematics to those in type 3 chondrites. In type 5 and 6 chondrites, oxygen isotope ratios of the four mineral phases plot along mass‐dependent fractionation lines that are consistent with the bulk average Δ17O of each chondrite group. The δ18O of three minerals, low‐Ca and high‐Ca pyroxene and plagioclase, are consistent with equilibrium fractionation at temperatures of 700–1000 °C. In most cases the δ18O values of olivine are higher than those expected from pyroxene and plagioclase, suggesting partial retention of premetamorphic values due to slower oxygen isotope diffusion in olivine than pyroxene during thermal metamorphism in ordinary chondrite parent bodies. 相似文献
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Rudaceous felsic to ultramafic clastic rocks of the Jones Creek Conglomerate are in tectonic contact with supracrustal mafic and ultramafic igneous rocks and associated fine‐grained sediments. All these rocks have a lower amphibolite facies mineralogy. Heterogeneously developed penetrative deformation has allowed sedimentary structures, including an unconformable contact between the Conglomerate and an adamellite, to be preserved in places. However, narrow, strike‐oriented zones containing blastomylonites and very flattened rudites normally characterize both contacts of the Conglomerate. Structural complexities within and at the contacts of the Conglomerate cast doubt on previous postulates that the Conglomerate separates an older from a younger supracrustal cycle. 相似文献
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A whole-moon numerical model of Europa is developed to simulate its thermal history. The thermal evolution covers three phases: (i) an initial, roughly 0.5 Gyr-long period of radiogenic heating and differentiation, (ii) a long period from 0.5 Gyr to 4 Gyr with continuing radiogenic heating but no tidal dissipative heating (TDH), and (iii) a final period covering the last 0.5 Gyr until the present, during which TDH is active. Hydrothermal plumes develop after the initial period of heating and differentiation and transport heat and salt from Europa’s silicate mantle to its ice shell. We find that, even without TDH, vigorous hydrothermal convection in the rocky mantle can sustain flow in an ocean layer throughout Europa’s history. When TDH becomes active, the ice shell melts quickly to a thickness of about 20 km, leaving an ocean 80 km or more deep. Parameterized convection in the ice shell is non-uniform spatially, changes over time, and is tied to the deeper ocean–mantle dynamics. We also find that the dynamics are affected by salt concentrations. An initially non-uniform salt distribution retards plume penetration, but is homogenized over time by turbulent diffusion and time-dependent flow driven by initial thermal gradients. After homogenization, the uniformly distributed salt concentrations are no longer a major factor in controlling plume transport. Salt transport leads to the formation of a heterogeneous brine layer and salt inclusions at the bottom of the ice shell; the presence of salt in the ice shell could strongly influence convection in that layer. 相似文献
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Understanding the dynamics of spatial and temporal variability of soil moisture at the regional scale and daily interval, respectively, has important implications for remote sensing calibration and validation missions as well as environmental modelling applications. The spatial and temporal variability of soil moisture was investigated in an agriculturally dominated region using an in‐situ soil moisture network located in central Saskatchewan, Canada. The study site evaluated three depths (5, 20, 50 cm) through 139 days producing a high spatial and temporal resolution data set, which were analysed using statistical and geostatistical means. Processes affecting standard deviation at the 5‐cm depth were different from the 20‐cm and 50‐cm depths. Deeper soil measurements were well correlated through the field season. Further analysis demonstrated that lag time to maximum correlation between soil depths increased through the field season. Temporal autocorrelation was approximately twice as long at depth compared to surface soil moisture as measured by the e‐folding frequency. Spatial correlation was highest under wet conditions caused by uniform rainfall events with low coefficient of variation. Overall soil moisture spatial and temporal variability was explained well by rainfall events and antecedent soil moisture conditions throughout the Kenaston soil moisture network. It is expected that the results of this study will support future remote sensing calibration and validation missions, data assimilation, as well as hydrologic model parameterization for use in agricultural regions. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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This paper analyses the institutional foundations of the mussel production sector in Galicia, which is one of the leading producers in the world. After demonstrating the importance of the sector and presenting the theoretical framework and an historical introduction, the paper formulates an agenda of institutional analysis topics from a positive perspective. This agenda includes the problem of the common pool, the role of the State, the legal norms, the property rights system, the organisation of the sector, the rules and public policies and the status quo. This paper presents a case analysis dealing with the relationships between institutions and economic organisation, and furnishes evidence and relevant knowledge for the elaboration of comparative analysis in the economics of natural resources. 相似文献